International
Tables for Crystallography Volume A Spacegroup symmetry Edited by M. I. Aroyo © International Union of Crystallography 2015 
International Tables for Crystallography (2015). Vol. A, ch. 1.4, pp. 4348
Section 1.4.1.4. Hermann–Mauguin symbols of the space groups
H. Wondratschek^{e}

The Hermann–Mauguin symbols, abbreviated as HM symbols in the following sections, were proposed by Hermann (1928, 1931) and Mauguin (1931), and introduced to the Internationale Tabellen zur Bestimmung von Kristallstrukturen (1935) according to the decision of the corresponding Programme Committee (Ewald, 1930). There are different kinds of HM symbols of a space group. One distinguishes short HM symbols, full HM symbols and extended HM symbols. The full HM symbols will be the basis of this description. They form the most transparent kind of HM symbols and their use will minimize confusion, especially for those who are new to crystallography.
As the name suggests, the short HM symbols are mostly shortened versions of the full HM symbols: some symmetry information of the full HM symbols is omitted such that these symbols are more convenient in daily use. The full HM symbol can be reconstructed from the short symbol. In the extended HM symbols the symmetry of the space group is listed in a more complete fashion (cf. Section 1.5.4 ). They are rarely used in crystallographic practice.
In the next section general features of the HM symbols will be discussed. Thereafter, the HM symbols for each crystal system will be presented in a separate section, because the appearance of the HM symbols depends strongly on the crystal system to which the space group belongs.
The Hermann–Mauguin symbol for a space group consists of a sequence of letters and numbers, here called the constituents of the HM symbol. The first constituent is always a symbol for the conventional cell of the translation lattice of the space group (cf. Section 1.3.2.1 for the definition of the translation lattice); the following constituents, namely rotations, screw rotations, rotoinversions, reflections and glide reflections, are marked by conventional symbols, cf. Table 2.1.2.1 .^{1} Together with the generating translations of the lattice, the set of these symmetry operations forms a set of generating symmetry operations of the space group. The space group can thus be generated from its HM symbol.
The symmetry operations of the constituents are referred to the lattice basis that is used conventionally for the crystal system of the space group. The kind of symmetry operation can be read from its symbol; the orientation of its geometric element, cf. de Wolff et al. (1989, 1992), i.e. its invariant axis or plane normal, can be concluded from the position of the corresponding constituent in the HM symbol, as the examples in the following sections will show. The origin is not specified. It is chosen by the user, who selects it in such a way that the matrices of the symmetry operations appear in the most convenient form. This is often, but not necessarily, the conventional origin chosen in the spacegroup tables of this volume. The choice of a different origin may make other tasks, e.g. the derivation of the space group from its generators, particularly easy and transparent.
The first constituent (the lattice symbol) characterizes the lattice of the space group referred to the conventional coordinate system. (Each lattice can be referred to a lattice basis, also called a primitive basis: the lattice vectors have only integer coefficients and the lattice is called a primitive lattice.) Lattice vectors with noninteger coefficients can occur if the lattice is referred to a nonprimitive basis. In this way similarities and relations between different spacegroup types are emphasized.
The lattice symbol of a primitive basis consists of an uppercase letter P (primitive). Lattices with conventional nonprimitive bases are called centred lattices, cf. Section 1.3.2.4 and Table 2.1.1.2 . For these other letters are used: if the ab plane of the unit cell is centred with a lattice vector , the letter is C; for ca centring [ as additional centring vector] the letter is B, and A is the letter for centring the bc plane of the unit cell by . The letter is F for centring all side faces of the cell with centring vectors , and . It is I (German: innenzentriert) for body centring by the vector and R for the rhombohedral centring of the hexagonal cell by the vectors and . In 1985, the letter S was introduced as a settingindependent `centring symbol' for monoclinic and orthorhombic Bravais lattices (cf. de Woff et al., 1985).
To describe the structure of the HM symbols the introduction of the term symmetry direction is useful.
Definition
A direction is called a symmetry direction of a crystal structure if it is parallel to an axis of rotation, screw rotation or rotoinversion or if it is parallel to the normal of a reflection or glidereflection plane. A symmetry direction is thus the direction of the geometric element of a symmetry operation when the normal of a symmetry plane is used for the description of its orientation.
The corresponding symmetry operations [the element set of de Wolff et al. (1989 & 1992)] specify the type of the symmetry direction. The symmetry direction is always a lattice direction of the space group; the shortest lattice vector in the symmetry direction will be called q.
If q represents both a rotation or screw rotation and a reflection or glide reflection, then their symbols are connected in the HM symbol by a slash `/', e.g. 2/m or 4_{1}/a etc.
The symmetry directions of a space group form sets of equivalent symmetry directions under the symmetry of the space group. For example, in a cubic space group the a, b and c axes are equivalent and form the set of six directions : [100], , [010] etc. Another set of equivalent directions is formed by the eight space diagonals : [111], . If there are twofold rotations around the twelve face diagonals , as in the space group of the crystal structure of NaCl, forms a third set of 12 symmetry directions.^{2}
Instead of listing the symmetry operations (element set) for each symmetry direction of a set of symmetry directions, it is sufficient to choose one representative direction of the set. In the HM symbol, generators for the element set of each representative direction are listed.
It can be shown that there are zero (triclinic space groups), one (monoclinic), up to two (trigonal and rhombohedral) or up to three (most other space groups) sets of symmetry directions in each space group and thus zero, one, two or three representative symmetry directions.
The nontranslation generators of a symmetry direction may include only one kind of symmetry operation, e.g. for twofold rotations 2 in space group P121, but they may also include several symmetry operations, e.g. 2, 2_{1}, m and a in space group C12/m1. To search for such directions it is helpful simply to look at the spacegroup diagrams to find out whether more than one kind of symmetry operation belongs to the generators of a symmetry direction. In general, only the simplest symbols are listed (simplestoperation rule): if we use `>' to mean `has priority', then pure rotations > screw rotations; pure rotations > rotoinversions; reflection .^{3} The space group mentioned above is conventionally called C12/m1 and not or C12/a1 or .
The position of a plane is fixed by one parameter if its orientation is known. On the other hand, fixing an axis of known direction needs two parameters. Glide components also show twodimensional variability, whereas there is only one parameter of a screw component. Therefore, reflections and glide reflections can better express the geometric relations between the symmetry operations than can rotations and screw rotations; reflections and glide reflections are more important for HM symbols than are rotations and screw rotations. The latter are frequently omitted to form short HM symbols from the full ones.
The second part of the full HM symbol of a space group consists of one position for each of up to three representative symmetry directions. To each position belong the generating symmetry operations of their representative symmetry direction. The position is thus occupied either by a rotation, screw rotation or rotoinversion and/or by a reflection or glide reflection.
The representative symmetry directions are different in the different crystal systems. For example, the directions of the basis vectors a, b and c are symmetry independent in orthorhombic crystals and are thus all representative, whereas a and b are symmetry equivalent and thus dependent in tetragonal crystals. All three directions are symmetry equivalent in cubic crystals; they belong to the same set and are represented by one of the directions. Therefore, the symmetry directions and their sequence in the HM symbols depend on the crystal system to which the crystal and thus its space group belongs.
Table 1.4.1.1 gives the positions of the representative latticesymmetry directions in the HM symbols for the different crystal systems.

Examples of full HM symbols are (from triclinic to cubic) , P12/c1, A112/m, F2/d2/d2/d, , , , P3m1, , , , and .
There are crystal systems, for example tetragonal, for which the highsymmetry space groups display symmetry in all symmetry directions whereas lowersymmetry space groups display symmetry in only some of them. In such cases, the symmetry of the `empty' symmetry direction is denoted by the constituent 1 or it is simply omitted. For example, instead of three symmetry directions in P4mm, there is only one in , for which the HM symbol is usually written . However, in some trigonal space groups the designation of a symmetry direction by `1' () is necessary to maintain the uniqueness of the HM symbols.^{4}
The HM symbols can not only describe the space groups in their conventional settings but they can also indicate the setting of the space group relative to the conventional coordinate system mentioned in Section 1.4.1.3.1. For example, the orthorhombic space group may appear as or or or or depending on its orientation relative to the conventional coordinate basis. On the one hand this is an advantage, because the HM symbols include some indication of the orientation of the space group and form a more powerful tool than being just a spacegroup nomenclature. On the other hand, it is sometimes not easy to recognize the spacegroup type that is described by an unconventional HM symbol. In Section 1.4.1.4.5 an example is provided which deals with this problem.
The full HM symbols describe the symmetry of a space group in a transparent way, but they are redundant. They can be shortened to the short HM symbols such that the set of generators is reduced to a necessary set. Examples will be displayed for the different crystal systems. The conventional short HM symbols still provide a unique description and enable the generation of the space group. For the monoclinic space groups with their many conventional settings they are not variable and are taken as standard for their spacegroup types. Monoclinic short HM symbols may look quite different from the full HM symbol, e.g. Cc instead of A1n1 or I1a1 or B11n or I11b.
The extended HM symbols display the additional symmetry that is often generated by lattice centrings. The full HM symbol denotes only the simplest symmetry operations for each symmetry direction, by the `simplest symmetry operation' rule; the other operations can be found in the extended symbols, which are treated in detail in Section 1.5.4 and are listed in Tables 1.5.4.3 (plane groups) and 1.5.4.4 (space groups).
From the HM symbol of the space group, the full or short HM symbol for a crystal class of a space group is obtained easily: one omits the lattice symbol, cancels all screw components such that only the symbol for the rotation is left and replaces any letter for a glide reflection by the letter m for a reflection. Examples are and .
If one is not yet familiar with the HM symbols, it is recommended to start with the orthorhombic space groups in Section 1.4.1.4.5. In the orthorhombic crystal system all crystal classes have the same number of symmetry directions and the HM symbols are particularly transparent. Therefore, the orthorhombic HM symbols are explained in more detail than those of the other crystal systems.
The following discussion treats mainly the HM symbols of space groups in conventional settings; for nonconventional descriptions of space groups the reader is referred to Chapter 1.5 .
There is no symmetry direction in a triclinic space group. Therefore, the basis vectors of a triclinic space group can always be chosen to span a primitive cell and the HM symbols are P1 (without inversions) and (with inversions). The HM symbol is the only one which displays the inversion explicitly. Sometimes nonconventional centred lattice descriptions may be used, especially when comparing crystal structures.
Monoclinic space groups have exactly one symmetry direction, often called the monoclinic axis. The b axis is the symmetry direction of the (most frequently used) conventional setting, called the baxis setting. Another conventional setting has c as its symmetry direction (caxis setting). In earlier literature, the uniqueaxis c setting was called the first setting and the uniqueaxis b setting the second setting (cf. Section 2.1.3.15 ). In addition to the primitive lattice P there is a centred lattice which is taken as C in the baxis setting, A in the caxis setting. The (possible) glide reflections are c (or a). In this volume, more settings are described, cf. Sections 1.5.4 and 2.1.3.15 and the spacegroup tables of Chapter 2.3 .
The full HM symbol consists of the lattice symbol and three possible positions for the symmetry directions. The symmetry in the a direction is described first, followed by the symmetry in the b direction and last in the c direction. The two positions of the HM symbol that are not occupied by the monoclinic symmetry direction are marked by 1. The symbol is thus similar to the orthorhombic HM symbol and the monoclinic axis is clearly visible. P1m1 or P11m may designate the same space group but in different settings. Pm11 is a possible but not conventional setting.
The short HM symbols of the monoclinic space groups are independent of the setting of the space group. They form the monoclinic standard symbols and are not variable: P2, , C2, Pm, Pc, Cm, Cc, P2/m, , C2/m, P2/c, and C2/c. Altogether there are 13 monoclinic spacegroup types.
There are several reasons for the many conventional settings.
To the orthorhombic crystal system belong the crystal classes 222, mm2 and 2/m2/m2/m with the Bravais types of lattices P, C, A, F and I. Four space groups with a P lattice belong to the crystal class 222, ten to mm2 and 16 to 2/m2/m2/m. Each of the basis vectors marks a symmetry direction; the lattice symbol is followed by characters representing the symmetry operations with respect to the symmetry directions along a, b and c.
We start with the full HM symbols. For a space group of crystal class 222 with a P lattice the HM symbol is thus `', where , , = 2 or . Conventionally one chooses a setting with the symbols P222, , and .
For the generation of the space groups of this crystal class only two nontranslational generators are necessary, say and . However, it is not possible to indicate in the HM symbol whether the axes and intersect or not. This is decided by the third (screw) rotation : if , the axes and intersect, if , they do not. For this reason, is sometimes called an indicator. However, any two of the three rotations or screw rotations can be taken as the generators and the third one is then the indicator. Mathematically each element of a generating set is a generator independent of its possible redundancy.
In the space groups of crystal class mm2 the two reflections or glide reflections are the generators, the twofold rotation or screw rotation is generated by composition of the (glide) reflections. The position of the rotation axis relative to the intersection line of the two planes as well as its screw component are determined uniquely by the glide components of the reflections or glide reflections.
The rotation or screw rotation in the HM symbols of space groups of the crystal class mm2 could be omitted, and were omitted in older HM symbols. Nowadays they are included to make the orthorhombic HM symbols more homogeneous. Conventional symbols are, among others, Pmm2, , Pba2 and .
The 16 space groups with a P lattice in crystal class 2/m2/m2/m are similarly obtained by starting with the letter P and continuing with the pointgroup symbol, modified by the possible replacements for 2 and a, b, c or n for m. The conventional symbols are, among others, P2/m2/m2/m, , , or . The symbols and designate different spacegroup types, as is easily seen by looking at the screw rotations: has screw axes in the direction of c only, has screw axes in all three symmetry directions.
If the lattice is centred, the constituents in the same symmetry direction are not unique. In this case, according to the `simplest symmetry operation' rule, in general the simplest operation is chosen, cf. Section 1.5.4 .
Examples
In the HM symbol there are in addition screw rotations in the first two symmetry directions; additional glide reflections b occur in the first, and n in the second and third symmetry directions.
In I2/b2/a2/m, all rotations 2 are accompanied by screw rotations 2_{1}; b and a are accompanied by c and m is accompanied by n. The symmetry operations that are not listed in the full HM symbol can be derived by composition of the listed operations with a centring translation, cf. Section 1.4.2.4.
There are two exceptions to the `simplest symmetry operation' rule. If the I centring is added to the P space groups of the crystal class 222, one obtains two different space groups with an I lattice, each has 2 and 2_{1} operations in each of the symmetry directions. One space group is derived by adding the I centring to the space group P222, the other is obtained by adding the I centring to a space group . In the first case the twofold axes intersect, in the second they do not. According to the rules both should get the HM symbol I222, but only the space group generated from P222 is named I222, whereas the space group generated from is called . The second exception occurs among the cubic space groups and is due to similar reasons, cf. Section 1.4.1.4.8.
The short HM symbols for the space groups of the crystal classes 222 and mm2 are the same as the full HM symbols. In the short HM symbols for the space groups of the crystal class 2/m2/m2/m the symbols for the (screw) rotations are omitted, resulting in the short symbols Pmmm, Pmma, Pmna, Pbam, Pnma, Cmcm and Ibam for the space groups mentioned above.
These are HM symbols of space groups in conventional settings. It is less easy to find the conventional HM symbol and the spacegroup type from an unconventional short HM symbol. This may be seen from the following example:
Question: Given the short HM symbols Pman, Pmbn and Pmcn, what are the conventional descriptions of their spacegroup types, and are they identical or different?
Answer: A glance at the HM symbols shows that the second symbol does not describe any spacegroup type at all. The second symmetry direction is b; the glide plane is perpendicular to it and the glide component may be , or , but not .
In this case it is convenient to define the intersection of the three (glide) reflection planes as the site of the origin. Then all translation components of the generators are zero except the glide components.
There are seven tetragonal crystal classes. The lattice may be P or I. The space groups of the three crystal classes 4, and 4/m have only one symmetry direction, [001]. The other four classes, 422, 4mm, and 4/m2/m2/m display three symmetry directions which are listed in the sequence [001], [100] and .^{5}
In the space groups of the crystal class 4, rotation or screw rotation axes run in direction [001]; in the space groups of crystal class these are rotoinversion axes ; and in crystal class 4/m both occur. The rotation 4 of the point group may be replaced by screw rotations 4_{1}, 4_{2} or 4_{3} in the space groups with a P lattice. If the lattice is Icentred, 4 and 4_{2} or 4_{1} and 4_{3} occur simultaneously, together with rotoinversions.
In the space groups of crystal class 4/m with a P lattice, the rotations 4 can be replaced by the screw rotations 4_{2} and the reflection m by the glide reflection n such that four spacegroup types with a P lattice exist: P4/m, , P4/n and . Two more are based on an I lattice: I4/m and . In all these six space groups the short HM symbols and full HM symbols are the same.
There are four crystal classes with three symmetry directions each. In the corresponding spacegroup symbols the constituents 2, 4 and m may be replaced by , with k = 1, 2 or 3, and a, b, c, n or d, respectively. The constituent persists. Full HM symbols of space groups are, among others, , , and .
The full and short HM symbols agree for the space groups that belong to the crystal classes 422, 4mm and . Only for the space groups of 4/m2/m2/m have the short HM symbols lost their twofold rotations or screw rotations leading, e.g., to the symbol instead of .
Example
In P4mm, to the primary symmetry direction [001] belong the rotation 4 and its powers, to the secondary symmetry direction [100] belongs the reflection . However, in the tertiary symmetry direction , there occur reflections m and glide reflections g with a glide vector . Such glide reflections are not listed in the `symmetry operations' blocks of the spacegroup tables if they are composed of a representing general position and an integer translation, as happens here (cf. Section 1.4.2.4 and Section 1.5.4 for a detailed discussion of the additional symmetry operations generated by combinations with integer translations). Glide reflections may have complicated glide vectors. If these do not fit the labels a, b, c, n or d, they are frequently called g.
Hexagonal and trigonal space groups are referred to a hexagonal coordinate system P with basis vector . The basis vectors a and b span a hexagonal net and form an angle of 120°. The sequence of the representatives of the (up to three) symmetry directions is [001], [100] and . Usually, the seven trigonal space groups of the rhombohedral lattice system (or rhombohedral space groups for short) are described either with respect to a hexagonal coordinate system (triple hexagonal cell) or to a rhombohedral coordinate system (primitive rhombohedral cell).
Trigonal space groups are characterized by threefold rotation or screw rotation or rotoinversion axes in [001]. There may be in addition 2 and 2_{1} axes in [100] or , but only in one of these two directions. The same holds for reflections m or glide reflections c. The different possibilities are:
Hexagonal space groups have either one or three representative symmetry directions. The space groups of crystal classes 6, and 6/m have [001] as their single symmetry direction for the axis 6 or 6_{k} for or , and for the plane m with its normal along [001]. The short and full HM symbols are the same. Examples are P6, , and .
Space groups of crystal classes 622, 6mm, and 6/m2/m2/m have the representative symmetry directions [001], [100] and . As opposed to the trigonal HM symbols, in the hexagonal HM symbols no symmetry direction is `empty' and occupied by `1'.
In space groups of the crystal classes 622, 6mm and the short and full HM symbols are the same; in 6/m2/m2/m the short symbols are deprived of the parts `2/' of the full symbols. The full HM symbol is shortened to the short HM symbol , the full HM symbol is shortened to . The two denote different spacegroup types.
The rhombohedral lattice may be understood as an Rcentred hexagonal lattice and then referred to the hexagonal basis. It has two kinds of symmetry directions, which coincide with the primary and secondary symmetry directions of the hexagonal lattice (owing to the R centrings, no symmetry operation along the tertiary symmetry direction of the hexagonal lattice is compatible with the rhombohedral lattice). On the other hand, the rhombohedral lattice may be referred to a (primitive) rhombohedral coordinate system with the lattice parameters a = b = c and α = β = γ. The HM symbol of a rhombohedral space group starts with R, its representative symmetry directions are or and or . In this section the rhombohedral primitive cell is used. The rotations 3 and the rotoinversions are accompanied by screw rotations 3_{1} and 3_{2}. Rotations 2 about horizontal axes always alternate with 2_{1} screw rotations and reflections m are accompanied by different glide reflections g with unconventional glide components. The additional operations mentioned are not listed in the full HM symbols.
The seven rhombohedral space groups belong to the five crystal classes 3, , 32, 3m and . In R3 and only the first of the symmetry directions is occupied and listed in the full and short HM symbols. In the space groups of the other crystal classes the second symmetry direction is occupied by `2' or `m' or `c' or `2/m' or `2/c', leading to the full HM symbols R32, R3m, R3c, and . In the short HM symbols the `2/' parts of the last two symbols are skipped: and .
There are five cubic crystal classes combined with the three types of lattices P, F and I in which the cubic space groups are classified. The two symmetry directions [100] and [111] are the representative directions in the space groups of the crystal classes 23 and . A third representative symmetry direction, , is added for space groups of the crystal classes 432, and .^{6}
In the full HM symbol the symmetry is described as usual. Examples are , , , , and finally No. 230, . The short HM symbols of the noncentrosymmetric space groups (those of crystal classes 23, 432 and ) are the same as the full HM symbols. In the short HM symbols of centrosymmetric space groups of the crystal classes and the rotations or screw rotations are omitted with the exception of the rotations 3 and rotoinversions which represent the symmetry in direction [111]. Thus, in the examples listed above, , and are the short HM symbols differing from the full HM symbols.
As in the orthorhombic space groups I222 and , there is the pair I23 and in which the `simplest symmetry operation' rule is violated. In both space groups twofold rotations and screw rotations around a, b and c occur simultaneously. In I23 the rotation axes intersect, in they do not. The first space group can be generated by adding the Icentring to the space group P23, the second is obtained by adding the Icentring to the space group .
References
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Hermann, C. (1928). Zur systematischen Strukturtheorie. I. Eine neue Raumgruppensymbolik. Z. Kristallogr. 68, 257–287.
Hermann, C. (1931). Bemerkung zu der vorstehenden Arbeit von Ch. Mauguin. Z. Kristallogr. 76, 559–561.
Mauguin, M. (1931). Sur le symbolisme des groupes de répétition ou de symétrie des assemblages cristallins. Z. Kristallogr. 76, 542–558.
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Wolff, P. M. de, Billiet, Y., Donnay, J. D. H., Fischer, W., Galiulin, R. B., Glazer, A. M., Senechal, M., Shoemaker, D. P., Wondratschek, H., Hahn, Th., Wilson, A. J. C. & Abrahams, S. C. (1989). Definition of symmetry elements in space groups and point groups. Report of the International Union of Crystallography AdHoc Committee on the Nomenclature of Symmetry. Acta Cryst. A45, 494–499.