International
Tables for Crystallography Volume B Reciprocal space Edited by U. Shmueli © International Union of Crystallography 2006 
International Tables for Crystallography (2006). Vol. B, ch. 5.1, pp. 545546
Section 5.1.7.1.1. Nonabsorbing crystals^{a}Laboratoire de MinéralogieCristallographie, Université P. et M. Curie, 4 Place Jussieu, F75252 Paris CEDEX 05, France 
Rocking curve. The geometrical construction in Fig. 5.1.3.5 shows that, in the Bragg case, the normal to the crystal surface drawn from the extremity of the incident wavevector intersects the dispersion surface either at two points of the same branch, , for branch 1, for branch 2, or at imaginary points. It was shown in Section 5.1.2.6 that the propagation of the wavefields inside the crystal is along the normal to the dispersion surface at the corresponding tie points. Fig. 5.1.3.5 shows that this direction is oriented towards the outside of the crystal for tie points and . In a very thick crystal, these wavefields cannot exist because there is always a small amount of absorption. One concludes that in the thickcrystal case and in reflection geometry, only one wavefield is excited inside the crystal. It corresponds to branch 1 on the lowangle side of the rocking curve and to branch 2 on the highangle side. Using the same approximations as in Section 5.1.6.2, the amplitude of the wave reflected at the crystal surface is obtained by applying the boundary conditions, which are particularly simple in this case:
The reflecting power is given by an expression similar to (5.1.6.7): where the expression for is given by (5.1.3.12), and j = 1 or 2 depending on which wavefield propagates towards the inside of the crystal. When the normal to the entrance surface intersects the dispersion surface at imaginary points, i.e. when , and there is total reflection. Outside the totalreflection domain, the reflecting power is given by
The rocking curve has the well known tophat shape (Fig. 5.1.7.1). Far from the totalreflection domain, the curve can be approximated by the function

Theoretical rocking curve in the reflection case for a nonabsorbing thick crystal in terms of the deviation parameter. 
Width of the totalreflection domain. The width of the totalreflection domain is equal to and its angular width is therefore equal, using (5.1.3.5), to 2δ, where δ is given by (5.1.3.6). It is proportional to the structure factor, the polarization factor C and the square root of the asymmetry factor . Using an asymmetric reflection, it is therefore possible to decrease the width at wish. This is used in monochromators to produce a pseudo plane wave [see, for instance, Kikuta & Kohra (1970)]. It is possible to deduce the value of the form factor from very accurate measurements of the rocking curve; see, for instance, Kikuta (1971).
Integrated intensity. The integrated intensity is defined by (5.1.6.8):
Penetration depth. Within the domain of total reflection, there are two wavefields propagating inside the crystal with imaginary wavevectors, one towards the inside of the crystal and the other one in the opposite direction, so that they cancel out and, globally, no energy penetrates the crystal. The absorption coefficient of the waves penetrating the crystal is where is the value taken by [equation (5.1.3.8)] in the Bragg case.
The penetration depth is a minimum at the middle of the reflection domain and at this point it is equal to . This attenuation effect is called extinction, and is called the extinction length. It is a specific property owing to the existence of wavefields. The resulting propagation direction of energy is parallel to the crystal surface, but with a cross section equal to zero: it is an evanescent wave [see, for instance, Cowan et al. (1986)].
References
Cowan, P. L., Brennan, S., Jach, T., Bedzyk, M. J. & Materlik, G. (1986). Observations of the diffraction of evanescent Xrays at a crystal surface. Phys. Rev. Lett. 57, 2399–2402.Kikuta, S. (1971). Determination of structure factors of Xrays using halfwidths of the Bragg diffraction curves from perfect single crystals. Phys. Status Solidi B, 45, 333–341.
Kikuta, S. & Kohra, K. (1970). Xray collimators using successive asymmetric diffractions and their applications to measurements of diffraction curves. I. General considerations on collimators. J. Phys. Soc. Jpn, 29, 1322–1328.