International
Tables for
Crystallography
Volume D
Physical properties of crystals
Edited by A. Authier

International Tables for Crystallography (2006). Vol. D, ch. 1.7, p. 182

Table 1.7.2.2 

B. Boulangera* and J. Zyssb

aLaboratoire de Spectrométrie Physique, Université Joseph Fourier, 140 avenue de la Physique, BP 87, 38 402 Saint-Martin-d'Hères, France, and bLaboratoire de Photonique Quantique et Moléculaire, Ecole Normale Supérieure de Cachan, 61 Avenue du Président Wilson, 94235 Cachan, France
Correspondence e-mail:  benoitb@satie-bourgogne.fr

Table 1.7.2.2| top | pdf |
Nonzero χ(2) coefficients and equalities between them in the general case

Symmetry classχ(2) nonzero elements
Triclinic  
C1 (1) All 27 elements are independent and nonzero
   
Monoclinic  
C2 (2) (twofold axis parallel to z) [xyz], [xzy], [xxz], [xzx], [yyz], [yzy], [yxz], [yzx], [zxx], [zyy], [zzz], [zxy], [zyx]
Cs (m) (mirror perpendicular to z) [xxx], [xyy], [xzz], [xxy], [xyx], [yxx], [yyy], [yzz], [yxy], [yyx], [zyz], [zzy], [zxz], [zzx]
   
Orthorhombic  
C2v (mm2) (twofold axis parallel to z) [xzx], [xxz], [yyz], [yzy], [zxx], [zyy], [zzz]
D2 (222) [xyz], [xzy], [yzx], [yxz], [zxy], [zyx]
   
Tetragonal  
C4 (4) [xyz=-yxz], [xzy=-yzx], [xzx=yzy], [xxz=yyz], [zxx=zyy], [zzz], [zxy=-zyx]
S4 ([\bar 4]) [xyz=yxz], [xzy=yzx], [xzx=-yzy], [xxz=-yyz], [zxx=-zyy], [zxy=zyx]
D4 (422) [xyz=-yxz], [xzy=-yzx], [zxy=-zyx]
C4v (4mm) [xzx=yzy], [xxz=yyz], [zxx=zyy], [zzz]
D2d ([\bar 4 2 m]) [xyz=yxz], [xzy=yzx], [zxy=zyx]
   
Hexagonal  
C6 (6) [xyz=-yxz], [xzy=-yzx], [xzx=yzy], [xxz=yyz], [zxx=zyy], [zzz], [zxy=-zyx]
C3h ([\bar 6]) [xxx=-xyy=-yxy=-yyx], [yyy=-yxx=] [-xyx=-xxy]
D6 (622) [xyz=-yxz], [xzy=-yzx], [zxy=-zyx]
C6v (6mm) [xzx=yzy], [xxz=yyz], [zxx=zyy], [zzz]
D3h ([\bar 6 2 m]) (mirror perpendicular to x) [yyy=-yxx=-xxy=-xyx]
   
Trigonal  
C3 (3) [xxx=-xyy=-yyx=-yxy], [xyz=-yxz], [xzy=-yzx], [xzx=yzy], [xxz=yyz], [yyy=-yxx=-xxy=-xyx], [zxx=zyy], [zzz], [zxy=-zyx]
D3 (32) [xxx=-xyy=-yyx=-yxy], [xyz=-yxz], [xzy=-yzx], [zxy=-zyx]
C3v (3m) (mirror perpendicular to x) [yyy=-yxx=-xxy=-xyx], [xzx=yzy], [xxz=yyz], [zxx=zyy, zzz]
   
Cubic  
T (23), Td ([\bar 4 3 m]) [xyz=xzy=yzx=yxz=zxy=zyx]
O (432) [xyz=-xzy=yzx=-yxz=zxy=-zyx]