International
Tables for Crystallography Volume D Physical properties of crystals Edited by A. Authier © International Union of Crystallography 2013 |
International Tables for Crystallography (2013). Vol. D, ch. 1.10, pp. 246-248
Section 1.10.1. Quasiperiodic structures^{a}Institute for Theoretical Physics, University of Nijmegen, 6524 ED Nijmegen, The Netherlands |
Many materials are known which show a well ordered state without lattice translation symmetry, often in a restricted temperature or composition range. This can be seen in the diffraction pattern from the appearance of sharp spots that cannot be labelled in the usual way with three integer indices. The widths of the peaks are comparable with those of perfect lattice periodic crystals, and this is a sign that the coherence length is comparable as well.
A typical example is K_{2}SeO_{4}, which has a normal lattice periodic structure above 128 K with space group Pcmn, but below this temperature shows satellites at positions , where is an irrational number, which in addition depends on temperature. These satellites cannot be labelled with integer indices with respect to the reciprocal basis , , of the structure above the transition temperature. Therefore, the corresponding structure cannot be lattice periodic.
The diffraction pattern of K_{2}SeO_{4} arises because the original lattice periodic basic structure is deformed below 128 K. The atoms are displaced from their positions in the basic structure such that the displacement itself is again periodic, but with a period that is incommensurate with respect to the lattice of the basic structure.
Such a modulated structure is just a special case of a more general type of structure. These structures are characterized by the fact that the diffraction pattern has sharp Bragg peaks at positions that are linear combinations of a finite number of basic vectors: Structures that have this property are called quasiperiodic. The minimal number n of basis vectors such that all are integers is called the rank of the structure. If the rank is three and the vectors do not all fall on a line or in a plane, the structure is just lattice periodic. Lattice periodic structures form special cases of quasiperiodic structures. The collection of vectors forms the Fourier module of the structure. For rank three, this is just the reciprocal lattice of the lattice periodic structure.
The definition given above results in some important practical difficulties. In the first place, it is not possible to show experimentally that a wavevector has irrational components instead of rational ones, because an irrational number can be approximated by a rational number arbitrarily well. Very often the wavevector of the satellite changes with temperature. It has been reported that in some compounds the variation shows plateaux, but even when the change seems to be continuous and smooth one can not be sure about the irrationality. On the other hand, if the wavevector jumps from one rational position to another, the structure would always be lattice periodic, but the unit cell of this structure would vary wildly with temperature. This means that, if one wishes to describe the incommensurate phases in a unified fashion, it is more convenient to treat the wavevector as generically irrational. This experimental situation is by no means dramatic. It is similar to the way in which one can never be sure that the angles between the basis vectors of an orthorhombic lattice are really 90°, although this is a concept that no-one has problems in understanding.
A second problem stems from the fact that the wavevectors of the Fourier module are dense. For example, in the case of K_{2}SeO_{4} the linear combinations of and cover the c axis uniformly. To pick out a basis here could be problematic, but the intensity of the spots is usually such that choosing a basis is not a problem. In fact, one only observes peaks with an intensity above a certain threshold, and these form a discrete set. At most, the occurrence of scale symmetry may make the choice less obvious.
One may distinguish various families of quasiperiodic systems. [Sometimes these are also called incommensurate systems if they are not lattice periodic (Janssen & Janner, 1987).] It is not a strict classification, because one may have intermediate cases belonging to more than one family as well. Here we shall consider a number of pure cases.
An incommensurately modulated structure or incommensurate crystal (IC) phase is a periodically modified structure that without the modification would be lattice periodic. Hence there is a basic structure with space-group symmetry. The periodicity of the modification should be incommensurate with respect to the basic structure. The position of the jth atom in the unit cell with origin at the lattice point is ().
For a displacive modulation, the positions of the atoms are shifted from a lattice periodic basic structure. A simple example is a structure that can be derived from the positions of the basic structure with a simple displacement wave. The positions of the atoms in the IC phase are then Here the modulation wavevector has irrational components with respect to the reciprocal lattice of the basic structure. One haswhere at least one of α, β or γ is irrational. A simple example is the function , where is the polarization vector and is the phase of the modulation. The diffraction pattern of the structure (1.10.1.2) shows spots at positionsTherefore, the rank is four and . In a more general situation, the components of the atom positions in the IC phase are given byHere the vectors belong to the Fourier module of the structure. Then there are vectors such that any spot in the diffraction pattern can be written asand the rank is . The peaks corresponding to the basic structure [the combinations of the three reciprocal-lattice vectors ()] are called the main reflections, the other peaks are satellites. For the latter, at least one of the is different from zero.
A second type of modulation is the occupation or composition modulation. Here the structure can again be described on the basis of a basic structure with space-group symmetry. The basic structure positions are occupied with a certain probability by different atom species, or by molecules in different orientations. In CuAu(II), the two lattice positions in a b.c.c. structure are occupied by either Cu and Au or by Au and Cu with a certain probability. This probability function is periodic in one direction with a period that is not a multiple of the lattice constant. In NaNO_{2}, the NO_{2} molecules are situated at the centre of the orthorhombic unit cell. There are two possible orientations for the V-shaped molecule, and the probability for one of the orientations is a periodic function with periodicity along the a axis. In this case, the modulation wavevector has a component that strongly depends on temperature in a very narrow temperature range.
If the probability of finding species A in position or of finding one orientation of a molecule in that point is given by , the probability for species B or the other orientation is of course . In the diffraction pattern, the spots belong to the Fourier module with basic vectors , , and . The analogous expression for a more general situation with more modulation wavevectors, or with more species or orientations, is a straightforward generalization.
The first examples of IC phases were found in magnetic systems (see Section 1.5.1.2.3 ). For example, holmium has a spiral spin arrangement with a periodicity of the spiral that does not fit with the underlying lattice. For the component () of the magnetic moment at position one has in an incommensurate magnetic system a superposition of wavesThe most general expression iswhere is the Fourier module (1.10.1.1).
A following class of quasiperiodic materials is formed by incommensurate composite structures. To this belong misfit structures, intercalates and incommensurate adsorbed layers. An example is Hg_{3−x}AsF_{6}. This consists of a subsystem of AsF_{6} octahedra forming a (modulated) tetragonal system and two other subsystems consisting of Hg chains, one system of chains in the x direction and one in the y direction. Because the average spacing between the Hg atoms is irrational with respect to the lattice constant of the host AsF_{6} system in the same direction, the total structure does not have lattice periodicity in the a or b direction.
In general, there are two or more subsystems, labelled by , and the atomic positions are given bywhere belongs to the th lattice, and where the modulation is a quasiperiodic displacement from the basic structure. The diffraction pattern has wavevectorsEach of the reciprocal-lattice vectors belongs to the Fourier module and can be expressed as a linear combination with integer coefficients of the n basis vectors .
Very often, composite structures consist of a host system in the channels of which another material diffuses with a different, and incommensurate, lattice constant. Examples are layer systems in which foreign atoms intercalate. Another type of structure that belongs to this class is formed by adsorbed monolayers, for example a noble gas on a substrate of graphite. If the natural lattice constant of the adsorbed material is incommensurate with the lattice constant of the substrate, the layer as a whole will be quasiperiodic.
In general, the subsystems can not exist as such. They form idealized lattice periodic structures. Because of the interaction between the subsystems the latter will, generally, become modulated, and even incommensurately modulated because of the mutual incommensurability of the subsystems. The displacive modulation will, generally, contain wavevectors that belong to the Fourier module (1.10.1.10). However, in principle, additional satellites may occur due to other mechanisms, and this increases the rank of the Fourier module.
The last class to be discussed here is that of quasicrystals. In 1982 it was found (Shechtman et al., 1984) that in the diffraction pattern of a rapidly cooled AlMn alloy the spots were relatively sharp and the point-group symmetry was that of an icosahedron, a group with 120 elements and one that can not occur as point group of a three-dimensional space group. Later, ternary alloys were found with the same symmetry of the diffraction pattern, but with spots as sharp as those in ordinary crystals. These structures were called quasicrystals. Others have been found with eight-, ten- or twelvefold rotation symmetry of the diffraction pattern. Such symmetries are also noncrystallographic symmetries in three dimensions. Sometimes this noncrystallographic symmetry is considered as characteristic of quasicrystals.
Mathematical models for quasicrystals are quasiperiodic two- and three-dimensional tilings, plane or space coverings, without voids or overlaps, by copies of a finite number of `tiles'. Examples are the Penrose tiling or the standard octagonal tiling in two dimensions, and a three-dimensional version of the Penrose tiling, a quasiperiodic space filling by means of two types of rhombohedra. For the Penrose tiling, all spots of the diffraction pattern are linear combinations of the five basis vectorsBecause the sum of these five vectors is zero, the rank of the spanned Fourier module is four. The Fourier module of the standard octagonal tiling is spanned byThe rank of the Fourier module is also four. The rank of the Fourier module of the three-dimensional Penrose tiling, consisting of two types of rhombohedra with a ratio of volumes of , is six and basis vectors point to the faces of a regular dodecahedron.
An atomic model can be obtained by decorating the tiles with atoms, each type of tile in a specific way. Some quasicrystals can really be considered as decorated tilings.
A simple example of a quasiperiodic function is obtained in the following way. Consider a function of n variables which is periodic with period one in each variable.Now take n mutually irrational numbers and define the function with one variable asBecause of the irrationality, the function is not periodic. If we consider the Fourier transform of we getand consequentlywhich proves that the function is quasiperiodic of rank n with n reciprocal-basis vectors in one dimension.
The quasiperiodic function is therefore the restriction to the line in n-dimensional space. This is a general situation. Each quasiperiodic function can be obtained as the restriction of a periodic function in n dimensions to a subspace that can be identified with the physical space. We denote the n-dimensional space in which one finds the lattice periodic structure (the superspace) by , the physical space by and the additional space, called internal space, by , such that is the direct sum of and . In the field of quasicrystals, one often uses the name parallel space for and perpendicular space for .
On the other hand, one can embed the quasiperiodic function in superspace, which means that one constructs a lattice periodic function in n dimensions such that its restriction to physical space is the quasiperiodic function. Take as an example the displacively modulated structure of equation (1.10.1.2). Compare this three-dimensional structure with the array of linesin four-dimensional space. The restriction to the three-dimensional hyperplane gives exactly the structure (1.10.1.2). Moreover, the four-dimensional array of lines is lattice periodic. Because is periodic, the array is left invariant if one replaces t by , and for every lattice vector of the basic structure the array is left invariant if one replaces simultaneously t by . This means that the array is left invariant by all four-dimensional lattice vectors of the lattice with basisIndeed the quasiperiodic IC phase is the restriction to () of the lattice periodic function in four dimensions.
The reciprocal basis for (1.10.1.18) consists of the basis vectorsThese span the reciprocal lattice . The projection of this basis on consists of the four vectors and , and these form the basis for the Fourier module of the quasiperiodic structure.
This is a well known situation. From the theory of Fourier transformation one knows that the projection of the Fourier transform of a function in n dimensions on a d-dimensional subspace is the Fourier transform of the restriction of that n-dimensional function to the same d-dimensional subspace. This gives a way to embed the quasiperiodic structure in a space with as many dimensions as the rank of the Fourier module. One considers the basis of the Fourier module as the projection of n linearly independent vectors in n-dimensional space. This means that for every vector of the Fourier module one has exactly one reciprocal-lattice vector in . Suppose the quasiperiodic structure is given by some function, for example the density . ThenOne may define a function in n-dimensional space bywhere is the unique reciprocal-lattice vector that is projected on the Fourier module vector . It is immediately clear that the restriction of to physical space is exactly . Moreover, the function is lattice periodic with lattice , for which is the reciprocal lattice.
This construction can be performed in the following equivalent way. Consider a point in physical space, where one has the quasiperiodic function . The Fourier module of this function is the projection on physical space of the n-dimensional reciprocal lattice with basis vectors (). The reciprocal lattice corresponds to the direct lattice . A point r in can also be considered as an element (r, 0) in n-dimensional space. By the translations of , this point is equivalent with a point with lattice coordinatesin the unit cell of , where Frac(x) is x minus the largest integer smaller than x. If one puts , the function determines the function in the unit cell, and consequently in the whole n-dimensional space . This means that all the information about the structure in is mapped onto the information inside the n-dimensional unit cell. The information in three dimensions is exactly the same as that in superspace. Only the presentation is different.
In the case in which the crystal consists of point atoms, the corresponding points in d-dimensional physical space are the intersection of ()-dimensional hypersurfaces with . For displacively modulated IC phases in three dimensions with one modulation wavevector, one has , and the hypersurfaces are just lines in superspace, as we have seen. For more independent modulation vectors the dimension of the hypersurfaces is larger than one. In this case, as often in the case of composite structures, the ()-dimensional surfaces do not have borders. This in contrast to quasicrystals, where they are bounded. All these hypersurfaces for which the intersection with physical space gives the atomic positions are called atomic surfaces.
Physical properties of aperiodic but quasi-periodic structures are partly determined by their symmetry, which can be formulated using the superspace approach. Here we deal mainly with such symmetry-related properties. A more extensive view is given in Janssen et al. (2007).
References
Janssen, T., Chapuis, G. & de Boissieu, M. (2007). Aperiodic Crystals, from Incommensurate Phases to Quasicrystals. Oxford University Press.Janssen, T. & Janner, A. (1987). Incommensurability in crystals. Adv. Phys. 36, 519–624.
Shechtman, D., Blech, I., Gratias, D. & Cahn, J. W. (1984). Metallic phase with long-range orientational order and no translational symmetry. Phys. Rev. Lett. 53, 1951–1953.