International
Tables for Crystallography Volume D Physical properties of crystals Edited by A. Authier © International Union of Crystallography 2013 |
International Tables for Crystallography (2013). Vol. D, ch. 2.2, p. 317
Section 2.2.5. The free-electron (Sommerfeld) model^{a}Institut für Materialchemie, Technische Universität Wien, Getreidemarkt 9/165-TC, A-1060 Vienna, Austria |
The free-electron model corresponds to the special case of taking a constant potential in the Schrödinger equation (2.2.4.1). The physical picture relies on the assumption that the (metallic) valence electrons can move freely in the field of the positively charged nuclei and the tightly bound core electrons. Each valence electron moves in a potential which is nearly constant due to the screening of the remaining valence electrons. This situation can be idealized by assuming the potential to be constant []. This simple picture represents a crude model for simple metals but has its importance mainly because the corresponding equation can be solved analytically. By rewriting equation (2.2.4.1), we have where in the last step the constants are abbreviated (for later convenience) by . The solutions of this equation are plane waves (PWs) where C is a normalization constant which is defined from the integral over one unit cell with volume . The PWs satisfy the Bloch condition and can be written (using the bra–ket notation) as From (2.2.5.1) we see that the corresponding energy (labelled by ) is given by
In this context it is useful to consider the momentum of the electron, which classically is the vector , where m and are the mass and velocity, respectively. In quantum mechanics we must replace by the corresponding operator .
Thus a PW is an eigenfunction of the momentum operator with eigenvalue . Therefore the vector is also called the momentum vector. Note that this is strictly true for a vanishing potential but is otherwise only approximately true (referred to as pseudomomentum).
Another feature of a PW is that its phase is constant in a plane perpendicular to the vector (see Fig. 2.2.5.1). For this purpose, consider a periodic function in space and time, which has a constant phase factor within such a plane. We can characterize the spatial part by within this plane. Taking the nearest parallel plane (with vector ) for which the same phase factors occur again but at a distance away (with the unit vector normal to the plane), then must differ from by . This is easily obtained from (2.2.5.7) by multiplication with leading to Consequently is the wavelength and thus the vector is called the wavevector or propagation vector.